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In NMC cathodes, the reversible insertion (lithiation) and extraction (delithiation) of lithium ions during battery discharge and charge are facilitated by redox reactions involving changes in the oxidation states of atoms within the oxide structure.• Traditional View (Cationic Redox): Historically, this capacity was attributed primarily to changes in the oxidation states of the transition metal cations (Ni, Mn, Co) – termed cationic redox. Transition metals.
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